My own personal experience with organic and preservative free wines has largely been very positive.There are a few I think you should try, including this Italian branded "Zero" Vendemmia 2011 Sulphur Dioxide free wine I tried on the weekend. It has cherry and Christmas cake notes with a hint of smoke. It's retails at $29.99 a bottle or as it's advertised in my local for $22.99 as a part of a 6-pack. So whilst it's not necessarily a "weekday" wine - I have no issue to spend the extra dollars on something I know I am going to enjoy, and something a little more "green".
Another great preservative free wine is Australian made King Valley's La Cantina Sangiovese or Cabernet Sauvignon. You can buy La Cantina from Dan Murphy's or check their website out here
And perhaps a lesser known organic wine which I first tried at No 10 William St Winebar at Paddington, called Hochkirch Maximus Pinot Noir from Henty in Western Victoria. You can pick up it up by the bottle or case from Organic Wine's website which you can check out by clicking here
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